Evolution of organo-cyanometallate cages: Supramolecular architectures and new [Cs.sup.+]-specific receptors
Article Abstract:
The ability of inorganic cyanometallate polymers to form useful complexes in homogeneous solution by using organometallic building blocks is described. This organometallic method to cyanometallates has combined the best of both the organometallic and inorganic realms like solubility, control of charge, tunable inertness and rigidity.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2007
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Fascination with the conformational analysis of succinic acid, as evaluated by NMR spectroscopy, and why
Article Abstract:
The preferences of succinic acid in its various ionization states, not only in water but also in less polar protic solvents, as well as range of aprotic solvents is determined with the help of NMR spectroscopy.The Coulomb's law appears to be violated at the sight of substantial gauche preferences by the dianion in aprotic solvents.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2006
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Characterization of enzyme motions by solution NMR relaxation dispersion
Article Abstract:
The NMR relaxation dispersion experiments are employed for the characterization of the protein motions and for explaining the thermodynamics associated with them. The technique is also found to be useful for the determination of the chemical shifts of the minor and hence can be used for studying several other enzyme functions.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2008
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